3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519)451-2500, Ext. 2222 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 11-6770-9 Issue date : 2002/09/12 Version : 7.01 Supersedes date : 2001/06/09 Prepared by: Environmental Health and Safety Services Department, 3M Canada Company. Telephone: (519) 452-6102, Fax: (519) 452-6015. ----------------------------------------------------------------------- 1 Product Identification ----------------------------------------------------------------------- Tradename: 3M FLEXIBLE DIAMOND - METAL BOND Product ID: 60-0000-6230-1 60-0000-6231-9 60-0000-6232-7 60-0000-6233-5 60-0000-6234-3 60-0000-6235-0 60-0000-6256-6 60-0000-6257-4 60-0000-6258-2 60-0000-6259-0 60-0000-6260-8 60-0000-6261-6 XC-0617-9239-3 XC-0617-9293-0 XC-0617-9294-8 XC-0617-9295-5 XC-0617-9541-2 XC-0617-9543-8 XC-0618-4109-1 XC-0618-4171-1 XC-0618-4126-5 XC-0618-4117-4 XC-0618-4248-7 XC-0618-4256-0 XC-0618-4294-1 XC-0618-4293-3 XC-0618-4330-3 XC-0618-4331-1 XC-0618-4332-9 XC-0618-4333-7 XC-0618-4356-8 XC-0618-5102-5 60-6500-1242-4 XC-0618-4801-3 XC-0618-4675-1 XC-0618-4679-3 XC-0618-4678-5 XC-0618-4652-0 XC-0618-4653-8 XC-0618-4504-3 XC-0618-4715-5 XC-0618-4614-0 Intended Use of Product: Abrasive Material Division: ABRASIVE SYSTEMS DIVISION ----------------------------------------------------------------------- 2 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- WOVEN COTTON OR POLYESTER CLOTH None 20.0 - 80.0 BACKING NICKEL 7440-02-0 15.0 - 60.0 DIAMOND 7782-40-3 0.2 - 15.0 3M FLEXIBLE DIAMOND - METAL BOND Page 2 of 7 ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- POLYESTER SCREEN None 2.0 - 10.0 Ingredient Statements: Products Include: 6001J, 6002J, 6008J, 6011J, 6018J, 6200J, 6201J, 6210J, 6220J, 6234J, 6237J, 6400J, 6401J, 6420J, 6450J, 6451J, 6455J, 6456J FINAL PRODUCT CAN BE LAMINATED TO A NYLON HOOK 'N LOOP SYSTEM PRESSURE SENSITIVE ADHESIVE OR A FOAMED PLASTIC SANDING BLOCK NOTE: WOVEN COTTON OR POLYESTER CLOTH BACKING has no CAS number. POLYESTER SCREEN has no CAS number. ----------------------------------------------------------------------- 3 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: WARNING: Contains a chemical which can cause cancer. (7440-02-0) (NTP anticipated human carcinogen, IARC possible human carcinogen 2B). See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Wash affected area with soap and water. Instructions for Inhalation: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. Instructions for Ingestion: Drink two glasses of water. Call a physician. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: Not applicable Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable Autoignition temperature: Not applicable Suitable Extinguishing Media: Water; Carbon Dioxide; Dry chemical; Foam; Exposure Hazards during Fire: No data available. 3M FLEXIBLE DIAMOND - METAL BOND Page 3 of 7 ----------------------------------------------------------------------- Combustion Products from Fire: Carbon monoxide and carbon dioxide; Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Special Instructions: Not applicable. ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: No data available. Spill Response: Not applicable. Methods for Disposal: As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. Dispose of waste product in a sanitary landfill. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: No data available. Incompatible Materials: None known. Ventilation: No data available. Fire Prevention: Not applicable. Use Instructions: A 3M study has shown that even under worst case conditions, the airborne nickel concentration is below both the existing and proposed Threshold Limit Values (TLV) for nickel metal. Use of a water lubricant is recommended to reduce the level of airborne nickel metal even further. ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- 3M FLEXIBLE DIAMOND - METAL BOND Page 4 of 7 ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact. Indirect vented goggles Safety glasses with side shields Hand Protection: Wear appropriate gloves when handling this material. Skin Protection: Avoid skin contact. Respiratory Protection: Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half-mask dust respirator; Ingestion (Prevention): Wash hands after handling and before eating. Do not ingest. Keep out of the reach of children. Recommended Ventilation: Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use in a well-ventilated area. If exhaust ventilation is not adequate, use appropriate respiratory protection. Ingredient Exposure Data ------------------------ WOVEN COTTON OR POLYESTER CLOTH BACKING (None) LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. NICKEL (7440-02-0) LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Inventory Certifications:: 2311114 EINECS - European Inventory of Existing Commercial Chemical Substances KE-25818 KECI - Korean Existing Chemicals Inventory PICCS - Philippines Inventory of Commercial Chemical Substances TSCA - Toxic Substances Control Act (USA) CICS - Chinese Inventory of Chemical Substances AICS - Australian Inventory of Chemical Substances DSL - Domestic Substances List (Canada) Exposure Limits:: ACGIH: TWA 1.5 mg/m3 as Ni, inhalable fraction; (Table A5) Regulatory Lists:: NTP CARCIN (Anticipated human carcinogen) IARC (Group 2B) Category: NICKEL ALLOYS EU Hazard Symbols and Risk Phrases:: EU - Adaptation 21 (Xn,Xi; R:40 Carc.Cat.3-43) 3M FLEXIBLE DIAMOND - METAL BOND Page 5 of 7 ----------------------------------------------------------------------- DIAMOND (7782-40-3) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. POLYESTER SCREEN (None) LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Solid; colour of backing varies by grade; No odour; Odour Threshold: No data available. pH: Not applicable Boiling point/boiling range: Not applicable Melting point/melting range: Not applicable Vapour pressure: Not applicable Water Solubility: Not applicable Partition coefficient (K o/w): No data available. Specific gravity: Not available Vapour density: Not applicable Volatile organic compounds: Not applicable Evaporation rate: Not applicable Viscosity: Not applicable ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition: Carbon monoxide and carbon dioxide; Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Mechanical eye irritation: Signs/symptoms can include pain, redness, tearing and corneal abrasion. 3M FLEXIBLE DIAMOND - METAL BOND Page 6 of 7 ----------------------------------------------------------------------- Effects from Skin Contact: Mechanical skin irritation: Signs/symptoms can include abrasion, redness, pain,and itching. Effects from Inhalation: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Ingestion is not a likely route of exposure to this product. Sensitization Information: No data available. Carcinogenicity: WARNING: Contains a chemical which can cause cancer. (7440-02-0) (NTP anticipated human carcinogen, IARC possible human carcinogen 2B). Mutagenicity: No data available. Reproductive Effects: No data available. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Ecotoxicity Data: No data available. Other Effects and Information: Not determined. ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: No data available. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------------------- 14 Transportation Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material 3M FLEXIBLE DIAMOND - METAL BOND Page 7 of 7 ----------------------------------------------------------------------- ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: D2A NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: This product is considered to be a manufactured article and therefore the Canadian Inventory listing is not applicable. ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Added product ids to the MSDS; Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---