3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519)451-2500, Ext. 2222 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 05-6259-5 Issue date : 04/16/2001 Version : 13.00 Supersedes date : 08/17/2000 Prepared by: Environmental Health and Safety Services Department, 3M Canada Company. Telephone: (519) 452-6102, Fax: (519) 452-6015. ----------------------------------------------------------------------- 1 Product Identification ----------------------------------------------------------------------- Tradename: 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, 05968, 05973, 05974 Product ID: 60-9800-1906-5 60-9800-1907-3 60-9800-2084-0 60-9800-2091-5 XC-0617-8279-0 Intended Use of Product: Glaze Division: AUTOMOTIVE AFTERMARKET ----------------------------------------------------------------------- 2 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 30.0 - 60.0 QUARTZ SILICA (CRYSTALLINE SILICA) 14808-60-7 10.0 - 30.0 HYDROTREATED LIGHT PETROLEUM 64742-47-8 10.0 - 30.0 DISTILLATES KAOLINITE 1318-74-7 7.0 - 13.0 SOLVENT-REFINED HEAVY PARAFFINIC 64741-88-4 1.0 - 5.0 PETROLEUM DISTILLATES OLEIC ACID 112-80-1 1.0 - 5.0 GLYCERIN 56-81-5 1.0 - 5.0 POLY(OXYETHYLENE)SORBITAN 9005-67-8 1.0 - 5.0 MONOSTEARATE FORMALDEHYDE 50-00-0 < 0.02 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 2 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- ----------------------------------------------------------------------- 3 Hazards Identification ----------------------------------------------------------------------- Critical Hazards Prolonged or repeated overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. WARNING: Contains a chemical which can cause cancer. (14808-60-7) (NTP anticipated human carcinogen, IARC probable human carcinogen 2A) WARNING: Contains a chemical which can cause cancer. (50-00-0) (NTP anticipated human carcinogen, ACGIH suspected human carcinogen A2, IARC probable human carcinogen 2A) See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical attention. Instructions for Inhalation: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. Instructions for Ingestion: Do not induce vomiting. Drink two glasses of water. Call a physician. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: 96.1 C PMCC Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available Autoignition temperature: Not available Suitable Extinguishing Media: Water; Dry chemical; Exposure Hazards during Fire: No unusual fire or explosion hazards are anticipated. Combustion Products from Fire: Carbon monoxide and carbon dioxide; 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 3 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- Fire Fighting Procedures: Water may be used to blanket the fire. ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: Observe precautions from other sections. Spill Response: Ventilate area. Contain spill. Cover with inorganic absorbent material. Collect spilled material. Clean up residue. Place in a closed container. Methods for Disposal: Incinerate in an industrial or commercial facility in the presence of a combustible material. Disposal alternative: Dispose of waste product in a facility permitted to accept chemical waste. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: Keep container closed when not in use. Incompatible Materials: Strong oxidizing agents; Explosion Prevention: Keep away from heat, sparks, open flame, and other sources of ignition. Use Instructions: Keep container tightly closed. ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact. Wear vented goggles. Hand Protection: Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: nitrile rubber; polyvinyl alcohol; fluoroelastomer (Viton); Skin Protection: Avoid prolonged or repeated skin contact. Respiratory Protection: Avoid breathing of vapours. Avoid breathing of dust created by cutting, sanding or grinding. Select one of the following NIOSH 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 4 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- approved respirators based on airborne concentration of contaminants: half-mask organic vapour respirator with dust/mist prefilter; full-face organic vapour respirator with dust/mist prefilter; Continuous spurring of dry buff pads may produce dust conditions in excess of the Threshold Limit Value (TLV) for crystaline silica. When cleaning or spurring a dry buff pad used with this product, use appropriate local exhaust to control dust, or use appropriate respiratory protection to avoid inhalation of dusts. Ingestion (Prevention): Do not ingest. Keep out of the reach of children. Recommended Ventilation: Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. Ingredient Exposure Data ------------------------ WATER (7732-18-5) LD50 (rat, oral): > 90 ml/kg QUARTZ SILICA (CRYSTALLINE SILICA) (14808-60-7) ACGIH TLV-TWA: 0.1 mg/m3 as quartz respirable dust. HYDROTREATED LIGHT PETROLEUM DISTILLATES (64742-47-8) Chemical Manufacturers' Recommended Guideline (CMRG) TWA Exposure Limit: 300 ppm KAOLINITE (1318-74-7) Specific Ingredient Data: No data available. SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES (64741-88-4) Chemical Manufacturers' Recommended Guideline (CMRG) TWA Exposure Limit: 5 mg/m3 OLEIC ACID (112-80-1) LD50 (rat, oral): 74,000 mg/kg GLYCERIN (56-81-5) LD50 (rat, oral): 12600 mg/kg LC50 (rat, inhalation): > 570 mg/m3 (1 hour) Ontario TWAEV: 10 mg/m3 Ontario STEV: 10 mg/m3 ACGIH TLV-TWA: 10 mg/m3 as mist POLY(OXYETHYLENE)SORBITAN MONOSTEARATE (9005-67-8) LD50 (rat, oral): > 60 g/kg Specific Ingredient Data: No data available. 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 5 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- FORMALDEHYDE (50-00-0) LD50 (rat, oral): 100 mg/kg LC50 (rat, inhalation/4 hours): 165 ppm PIN (Product Identification Number): UN 1198 Ontario TWAEV: 1 ppm 1.5 mg/m3 Ontario STEV: 2 ppm 3 mg/m3 ACGIH TLV-Ceiling: 0.37 mg/m3 0.3 ppm Specific Ingredient Data: LD50 (rabbit, dermal): 270 mg/kg ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Liquid; cream colour; mild solvent odour; Odour Threshold: No data available. pH: 7.8 - 8.5 Boiling point/boiling range: 65.6 - 100.0 C Melting point/melting range: Not available Vapour pressure: < 1 Air=1 Water Solubility: Complete Partition coefficient (K o/w): No data available. Specific gravity: 1.0 - 1.15 Water=1 Vapour density: > 1.00 Air=1 Volatile organic compounds: 1.88 lb/gal SCAQ443 Evaporation rate: 1.00 Water=1 Viscosity: 14000 - 22000 centipoise ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: None known. Materials to Avoid: Strong oxidizing agents; Hazardous Decomposition: Carbon monoxide and carbon dioxide; Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Mild Eye Irritation: signs/symptoms can include redness, swelling, pain, and tearing. 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 6 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- Effects from Skin Contact: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. Effects from Inhalation: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Silicosis: signs/symptoms can include shortness of breath and persistent coughing. Effects from Ingestion: Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. Sensitization Information: No data available. Carcinogenicity: WARNING: Contains a chemical which can cause cancer. (14808-60-7) (NTP anticipated human carcinogen, IARC probable human carcinogen 2A) WARNING: Contains a chemical which can cause cancer. (50-00-0) (NTP anticipated human carcinogen, ACGIH suspected human carcinogen A2, IARC probable human carcinogen 2A) Mutagenicity: No data available. Reproductive Effects: No data available. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Ecotoxicity Data: No data available. Other Effects and Information: Not determined. ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: No data available. 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 7 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------------------- 14 Transportation Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material International Dangerous Goods Classification -------------------------------------------- IMO Class: No data available. ICAO Class: No data available. ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: D2A XC-0617-8279-0: Exempt (Consumer Product) NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: The product on this MSDS, or all its components, is included on the following countries' chemical inventories, as noted: DSL - Domestic Substances List (Canada) AICS - Australian Inventory of Chemical Substances KECI - Korean Existing Chemicals Inventory TSCA - Toxic Substances Control Act (USA) EINECS - European Inventory of Existing Commercial Chemical Substances PICCS - Philippines Inventory of Commercial Chemical Substances CICS - Chinese Inventory of Chemical Substances ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- 3M(TM) PERFECT-IT(TM) II RUBBING COMPOUND P/N 05967, Page 8 of 8 05968, 05973, 05974 ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Formulation revision. Section 3 - Hazards Identification - Critical Hazards; Section 9 - Physical and Chemical Properties; Section 9 - Physical and Chemical Properties - Volatile organic compounds; Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---